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The New York Times Summer Internship Program: The New York Times 10-week summer internship program is open to all students interested in pursuing a career in journalism. New York City community. Newsroom Summer Internships Jobs . Some internships are limited to seniors or graduate students; others also accept juniors. Applicants must be authorized to work in the U. S. The salary for all internships is about $1,0. For those who want it, housing in New York is available in the dormitories of New York University at rates ranging from about $3. The 2. 01. 7 program will begin on Monday, June 5, with three days of orientation. The deadline to submit an application for the 2. Information about specific internships can be found by clicking on the links below. Individuals may apply for more than one internship. The program provides a summer of demanding work and high journalistic standards, with individual internships in reporting, in visual and interactive journalism and in video, and it offers copy- editing internships with placement by the Dow Jones News Fund. The reporting internship in New York is called the James Reston Reporting Fellowship, and the reporting internship in Washington, D. C., is named the David E. Rosenbaum Reporting Internship. Both are limited to college seniors and graduate students. The visual journalism program, covering graphics, art design, page design and photography, is called the Thomas Morgan Internship and is open to those in their junior year in college or higher. The copy editing internship program is coordinated through the Dow Jones News Fund Copy Editing program and is open to juniors and higher. The audience development internship in the newsroom, working with The Times’s social media editors, is open to juniors and higher. 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Causes, Effects and Control of Air Pollution. Essay on Air Pollution: Causes, Effects and Control of Air Pollution! The World Health Organization defines air pollution as “the presence of materials in the air in such concentration which are harmful to man and his environment.”In fact air pollution is the occurrence or addition of foreign particles, gases and other pollutants into the air which have an adverse effect on human beings, animals, vegetation, buildings, etc. Cause of Air Pollution: The various causes of air pollution are: (i) Combustion of natural gas, petroleum, coal and wood in industries, automobiles, aircrafts, railways, thermal plants, agricultural burning, kitchens, etc. The major cause of pollution in the urban areas is automobiles which inefficiently burn petroleum, releases 7. Air Pollution and its Control Measures 449 Spray tower Wet scrubber VOC control Catalytic converters Biofilters Absorption (scrubbing) Cryogenic condensers Vapor recovery systems Acid Gas/SO 2 control Wet scrubbers Dry scrubbers. Concentration of industries in one area is another major cause of air pollution. Effect of Air Pollutants: Air pollutants are broadly classified into particulate and gaseous. The particulate substances include solid and liquid particles. The gaseous include substances that are in the gaseous state at normal temperature and pressure. The air pollutants have adverse effect on human beings, animals, vegetation, buildings. Air pollutants also change earth’s climate. Aesthetic sense is also influenced by air pollutants. The different air pollutants and their effects are as follows: 1. Particulate Matter: It is of two types—settleable and suspended. The settleable dusts have a particle longer than 1. 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The World Health Organization defines air pollution as “the presence of materials in the air in such concentration which are harmful to man and his environment.” (i) Combustion of natural gas, petroleum, coal and wood in. In this lesson you will study about the major causes of pollution, their effects on our environment and the various measures that can be taken to control such pollutions. The third edition of Pollution has been once again updated and expanded to reflect the changes that have taken place in recent years, including new chapters on marine pollution, soils and contaminated land and the effects of air pollutant exposure on human health. A brief introduction on Environmental Pollution by M.Shanmugaraj M.E., Lecturer / Civil V.S.V.N. Polytechnic College, Virudhunagar, Tamil Nadu, India. Environmental Pollution - Causes, Effects and Control Measures 1. Environmental Pollution. Category Major causes Major symptoms Examples Atmospheric pollution Smoke, dust, exhaust fumes, toxic substances (such as. Chapter 6 Environmental Pollution Control Measures range of regulations and restrictions. At the national level, however, the. In human beings and animals it produces respiratory troubles.(iii) Particulate matter suspended in air, scatters and partly absorbs light. In industrial and urban areas, sunlight is reduced to 1/3 in summer and 2/3 in winter.(iv) At a concentration above 1. Lung fibrosis produced in other industries includes asbestosis (in asbestos industry), silicosis (stone grinders), siderosis (iron mill), coal miners’ pneumoconiosis, flour mill pneumoconiosis, etc. Carbon monoxide: It accounts for 5. It is formed by incomplete combustion of carbon fuels in various industries, motor vehicles, hearths, kitchens, etc. Carbon monoxide combines with haemoglobin of blood and impairs its oxygen carrying capacity. At higher concentration, carbon monoxide proves lethal. Sulphur Oxides: They occur mainly in the form of sulphur dioxide. It is produced in large quantity during smelting of metallic ores and burning of petroleum and coal in industries, thermal plants, home and motor vehicles. In the air, SO2 combines with water to form sulphurous acid (H2. SO3) which is the cause of acid rain. It causes chlorosis and necrosis of vegetation. Sulphur dioxide, above 1 ppm, affects human beings. It causes irritation to eyes and injury to respiratory tract. It results in discolouration and deterioration of buildings, sculptures, painted surfaces, fabrics, paper, leather, etc. Nitrogen Oxides: They are produced naturally through biological and non- biological activities from nitrates, nitrites, electric storms, high energy radiations and solar flares. Human activity forms nitrogen oxides in combustion process of industries, automobiles, incinerators and nitrogen fertilizers. Nitrogen oxides act on unsaturated hydrocarbons to form peroxy- acyl nitrates or PAN. It gives rise to photochemical smog. They cause eye irritation, respiratory troubles, blood congestion and dilation of arteries. Carbon dioxide: Due to excessive combustion activity, the content of C0. As carbon dioxide accumulates in the atmosphere it absorbs more and more of the reflected infrared radiation. This could cause an increase in temperature referred to as the green house effect. Melting polar ice caps and glaciers could cause sea levels to rise, flooding most of the major population centres and fertile lands. Phosgene and Methyl Isocyanate: Phosgene (COCl. Release of phosgene and MIC in industrial accident of Bhopal (Dec. Aerosols: They are widely used as disinfectants. Other sources are jet plane emissions which contain chlorofluorocarbons. Chlorofluorocarbons are also used in refrigeration and formation of certain types of solid plastic foams. Burning of plastics produces polychlorinated biphenyls (PCBs). The latter are persistent and pass into the food chain. Chlorofluorocarbons and carbon tetrachloride react with ozone layers of stratosphere and hence deplete the same. Photochemical oxidants: Hydrocarbons have carcinogen properties. Some of these are also harmful to plants because they cause senescence and abscission. In the presence of sunlight, hydrocarbons react with nitrogen oxides to produce ozone, peroxy- acyl nitrates, aldehydes and other compounds. Peroxy- acyl nitrates are a major constituent of air pollution. They cause eye irritation and respiratory diseases. Automobile Exhausts: They are one of the major sources of air pollution. The important pollutants are Carbon monoxide, Benzpyrene, Lead, Nitrogen oxides, Sulphur compounds and Ammonia. Pollen and Microbes: Excess of microbes in the atmosphere directly damage the vegetation, food articles and causes diseases in plants, animals and human beings. Excess of pollen causes allergic reactions in several human beings. The common reactions are also collectively called hay- fever. The important allergic pollen belong to Amaranthus spinosus, Chenopodium album, Cynodon dactylon, Ricinus communis, Sorghum vulgare, Prosopis chilensis etc. Control of Air Pollution: 1. Industrial estates should be established at a distance from residential areas. Use of tall chimneys shall reduce the air pollution in the surroundings and compulsory use of filters and electrostatic precipitators in the chimneys. Removal of poisonous gases by passing the fumes through water tower scrubber or spray collector. Use of high temperature incinerators for reduction in particulate ash production. Development and employment of non- combustive sources of energy, e. Use of non- lead antiknock agents in gasoline. Attempt should be made to develop pollution free fuels for automobiles, e. Automobiles should be fitted with exhaust emission controls. Industrial plants and refineries should be fitted with equipment for removal and recycling of wastes. Growing plants capable of fixing carbon monoxide, e. Phaseolus vulgaris, Coleus blumei, Daucus carota, Ficus variegata (Bidwell and Bebee, 1. Growing plants capable of metabolising nitrogen oxides and other gaseous pollutants, e. Vitis, Pimis, Jttniperus, Quercus, Pyrus, Robinia pseudo- acacia, Viburnum, Crataegus, Ribes, Rhamnus. Afforestation of the mining area on priority basis. Buffer solution - Wikipedia, the free encyclopedia. For an individual weak acid or weak base component, see Buffering agent. For uses not related to acid- base chemistry, see Buffer (disambiguation). A buffer solution (more precisely, p. H buffer or hydrogen ion buffer) is an aqueous solution consisting of a mixture of a weak acid and its conjugate base, or vice versa. Its p. H changes very little when a small or moderate amount of strong acid or base is added to it and thus it is used to prevent changes in the p. H of a solution. Buffer solutions are used as a means of keeping p. H at a nearly constant value in a wide variety of chemical applications. Many life forms thrive only in a relatively small p. H range so they utilize a buffer solution to maintain a constant p. H. In nature, the bicarbonate buffering system is used to regulate the p. H of blood. Principles of buffering. ACS ActiveView PDF Hi-Res Print, Annotate, Reference QuickView; PDF. See all Biochemistry ACS Editors' Choice articles. CLINICAL BIOCHEMISTRY Basic Concept of Clinical Biochemistry. Preparation of buffers: Standard buffer components like acid and its conjugate base. Practical Lesson No 2 BUFFERS AND BUFFER CAPACITY Reagents. Practical Lesson No 3. Chemistry 11 pH and Buffers - Advance Study Assignment Due on December 9, 2002 at noon 1. The pH of a 0.10 M solution of NaH2PO4 is 4.5. 1 Biochemistry I, Fall Term Sept 7, 2005 Lecture 4: Buffers & Polyprotic Acids Reading in Campbell: Chapter 2.3-2.6 Key Terms: Ii A word to our valued customers We are pleased to present to you the newest edition of Buffers: A Guide for the Preparation and Use of Buffers in Biological Systems. Buffers Biochemistry Pdf BookHA, and its conjugate base, A- Buffer solutions achieve their resistance to p. H change because of the presence of an equilibrium between the acid HA and its conjugate base A. Because of this, the hydrogen ion concentration increases by less than the amount expected for the quantity of strong acid added. Similarly, if strong alkali is added to the mixture the hydrogen ion concentration decreases by less than the amount expected for the quantity of alkali added. The effect is illustrated by the simulated titration of a weak acid with p. Ka = 4. 7. The relative concentration of undissociated acid is shown in blue and of its conjugate base in red. The p. H changes relatively slowly in the buffer region, p. H = p. Ka . The hydrogen ion concentration decreases by less than the amount expected because most of the added hydroxide ion is consumed in the reaction. OH. It can be defined as follows. With this definition the buffer capacity of a weak acid, with a dissociation constant Ka, can be expressed asdnd(p. H)=2. 3. 03(CAKa. The buffer capacity of a buffering agent is at a local maximum when p. It falls to 3. 3% of the maximum value at p. For this reason the useful range is approximately p. Ka . Buffer capacity is proportional to the concentration of the buffering agent, CA, so dilute solutions have little buffer capacity. Its buffer capacity can be expressed asdnd(p. H)=2. 3. 03(. They are concentration effects and reflect the fact that p. H is related to the logarithm of the hydrogen ion concentration. Applications. Many enzymes work only under very precise conditions; if the p. H moves outside of a narrow range, the enzymes slow or stop working and can denature. In many cases denaturation can permanently disable their catalytic activity. They are also used in chemical analysis. For alkaline buffers, a strong base such as sodium hydroxide may be added. Alternatively, a buffer mixture can be made from a mixture of an acid and its conjugate base. For example, an acetate buffer can be made from a mixture of acetic acid and sodium acetate. Similarly an alkaline buffer can be made from a mixture of the base and its conjugate acid. Citric acid is a useful component of a buffer mixture because it has three p. Ka values, separated by less than two. Chemistry/Biology 302 – Biochemistry: Exam 1 Practice Problems PLEASE NOTE: these questions come from several years of past Biochem tests. The buffer range can be extended by adding other buffering agents. The following mixtures (Mc. Ilvaine's buffer solutions) have a buffer range of p. Buffers Biochemistry Pdf FreeH 3 to 8. The equilibrium concentrations of these three components can be calculated in an ICE table. ICE table for a monoprotic acid. If strong alkali, such as sodium hydroxide, is added y will have a negative sign because alkali removes hydrogen ions from the solution. The second row, labelled C for change, specifies the changes that occur when the acid dissociates. The acid concentration decreases by an amount . This follows from the equilibrium expression. The third row, labelled E for equilibrium concentrations, adds together the first two rows and shows the concentrations at equilibrium. To find x, use the formula for the equilibrium constant in terms of concentrations: Ka=. The constant for dissociation of the first proton may be denoted as Ka. Ka. 2, etc. Citric acid, H3. A, is an example of a polyprotic acid as it can lose three protons. Equilibriump. Ka value. H3. A . The smaller the difference, the more the overlap. In the case of citric acid, the overlap is extensive and solutions of citric acid are buffered over the whole range of p. H 2. 5 to 7. 5. Calculation of the p. H with a polyprotic acid requires a speciation calculation to be performed. In the case of citric acid, this entails the solution of the two equations of mass balance. CA=. There are two non- linearsimultaneous equations in two unknown quantities . Many computer programs are available to do this calculation. The speciation diagram for citric acid was produced with the program Hy. SS. Ionic Equilibrium: A Mathematical Approach. Reactions of acids and bases in analytical chemistry. Translated by Masson, Mary R. Fundamentals of Acids, Bases, Buffers & Their Application to Biochemical Systems. Vogel's textbook of quantitative chemical analysis (5th ed.). Harlow: Pearson Education. Bibcode: 1. 96. 1JCh. Ed. 3. 8. 5. 59. C. Coordination Chemistry Reviews. 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Rule #1: Think before you speak. Tina, an office worker from Pennsylvania, tells the story of a boss who could never quite phrase a compliment nicely. I've never seen your hair look nice! What did you do?' She didn't come out and say, 'Your hair usually looks totally boring,' but it's what we all heard. Make a point not to overburden your coworkers by shirking your responsibilities. Jeanine from Vermont worked with a woman who clocked out at 4: 3. Her inability to do a full day's work slowed down our entire department. If a coworker has shut her office door, stay out––even if she doesn't look busy. Says Renee from New Orleans: . Most of the day, my office door was closed, but I always opened it around 4 and people would stop by for candy and a chat. Except for one coworker, who would knock on my door all day long. Any joke made at your coworker's expense—or worse, a customer's—probably isn't all that funny. Flight attendant Betty from California, author of Betty in the Sky with a Suitcase, spent a plane ride with two coworkers who went way too far. But remember that once you hit . Sarah from New York tells the story of Ralph, a mailroom worker who fired off an angry missive when someone swiped his lunch from the office refrigerator. Mark from Iowa works in an advertising office by day and writes horror stories by night. When a coworker found out about his nighttime gig, which earned him a nomination for a national book award, she chastised him for . Sure, last night's delicious cod dish would make a delightful lunch—but it's not nice to make coworkers suffer through your smelly meal. Cindy from Indiana worked with . Also skip smelly foods when you're ordering takeout. Rule #8: Watch your language, even when you're away from your desk. Especially when a client might witness or hear your bad behavior. Blythe from North Carolina worked in a call center, which meant most people in the office were on the phone for most of the day. One coworker was 1. Pottymouth's tirades. If clients see you clash with a coworker, you'll both come off as unprofessional. Treat your colleagues with respect and hopefully they'll follow your lead. Caitlyn in New York worked in clothing retail for two years and often butted heads with a particularly snippy coworker. Carl from Colorado, who works in construction, knows of two coworkers who lost their jobs after misusing company vehicles. One repairman drove the company van to a well- known drug house in the middle of the day; he was busted when the boss drove by on his way home for lunch. A second coworker was fired after getting a DUI while driving a company car. Even if your misdeeds are seemingly more innocent—say, mailing your grandma a care package from the office mailroom using the company's account number—remember that anything that might be considered stealing is grounds for dismissal. |
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